Rice, J. 773 799 Reduction of Organic Compounds With Diborane . A convenient synthesis of amines from olefins via hydroboration, In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution, Rational Design of a Well‐Defined Soluble Calcium Hydride Complex, The effects of chemical additives on the induction phase in solid-state thermal decomposition of ammonia borane, Magnesium borohydride: A new hydrogen storage material, Method of reducing and hydrogenating chemical compounds by reacting with alkali metal borohydrides, Reduction of organic compounds with diborane, Non-classical divalent lanthanide complexes, In situ process for preparing quaternary ammonium bicarbonates and quaternary ammonium carbonates, Hydroboration. XV. K. Smith Chem. Isolated 2 was shown to catalyze AB dehydrogenation, forming BN-containing products similar to 1, albeit at a slower rate. 773-799 ". Complex 1 (0.5 mol %, THF, 3 hrs, open system) promoted the dehydrocoupling of H 3 B⋅NH 3 (1.2 equiv of H 2 evolved by gas burette; Supporting Information, Figures S4–S7) to form oligomeric species such as B‐(cyclotriborazanyl)amine‐borane (BCTB), 3, 38 and insoluble polyamino‐borane. The Tetrahydrofuran Borine . Reaction of Diborane in Tetrahydrofuran With Selected Organic Compounds Containing Representative Functional Groups . Bug, typo or grammatical error reports about this page, please contact Mark R. Leach, the author, using mark@meta-synthesis.com. Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice. H. C. Brown, M. C. Desai, P. K. Jadhav JOC 1982, 47, pp. 870 871. 格物致知医药科技有限公司, B. Comments Reaction of Diborane in Tetrahydrofuran With Selected Organic Compounds Containing Representative Functional Groups, Solubility of Diborane- and Boron-containing Lithium Salts, Advances in Organoboron Chemistry--Prospects for Industry, Use of Complexes of Diborane and Organoboranes on a Laboratory and Industrial Scale, Increasing enatioselectivity in reductions with borane reagents, Stabilized deuteroborane-tetrahydrofuran complex, Stabilized Borane-Tetrahydrofuran Complex, Preparation method of high purity borane gas and application of borane gas, Increasing enantioselectivity in reductions with borane reagents, Stabilized borane-tetrahydrofuran complex, Convenient procedures for the laboratory preparation of borazine, [Me3Si][R‐CB11F11]—Synthesis and Properties, Lithium aluminum hydride, aluminum hydride and lithium gallium hydride, and some of their applications in organic and inorganic chemistry1, The reaction of organoboranes with chloramine and with hydroxylamine-O-sulfonic acid. 603 611. Please upgrade your Internet Explorer to a newer version. B. EC number: 237-881-8 | CAS number: 14044-65-6. Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. and Industry 1987, pp. 1637-1646. Guideline study, available as unpublished report, adequate for assessment. II. J. R. Elliott, W. L. Roth, G. F. Roedel and E. M. Boldebuck JACS 1952, 74, pp. This information has not been reviewed or verified by the Agency or any other authority. Advances in Organoboron Chemistry Prospects for Industry . 1958, 52, pp. Chem. A. Livasy, G. W. Schaeffer JACS 1955, 77, p. 2750. K. Smith Chem. Product Name Borane-tetrahydrofuran complex, 1M solution in THF, stabilized Cat No. H. E. Wirth, F. E. Massoth, D. X. Gilbert J. Phys. 61. 123 128 Use of Complexes of Diborane and Organoboranes on a Laboratory and Industrial Scale . 603-611. 61. Tetrahydrofuran--borane. Selective Reductions. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1.67 estimate) = 0.23 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 440.34 (Adapted Stein & Brown method) Melting Pt (deg C): 148.90 (Mean or Weighted MP) VP(mm Hg,25 deg C): 1.24E-007 (Modified Grain … A. Livasy, G. W. Schaeffer JACS 1955, 77, p. 2750. B: 1: C: 4: H: 11: O: 1 : Real, long lived, electronically neutral reagent chemical. Diisopinocampheylborane of High Optical Purity. ". Close Find out more on how we use cookies. Rice, J. © Mark R. Leach 1999 – Suggestions for links Diisopinocampheylborane of High Optical Purity. Real, long lived, electronically neutral reagent chemical. 1976, 76, pp. XV. ". Specific Gravity/Density:0.876 Molecular Formula:C4H11BO Molecular Weight:85.94 Section 10 - Stability and Reactivity Chemical Stability: Unstable. H. E. Wirth, F. E. Massoth, D. X. Gilbert J. Phys. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner. ". Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Reacts violently with water. Suggestions M. Follet Chem. H. C. Brown, P. Heim, N. M. Yoon JACS, 1970, 92, pp. (adsbygoogle = window.adsbygoogle || []).push({}); Hydride donor Lewis acid reducing agent (generic), Nucleophilic attack susceptible species (generic). Rev. Hydroboration-oxidation converts alkenes into alcohols: THF (tetrahydrofuran) is the solvent that is used to stabilize the dimer of BH 3 which is a flammable, toxic, and explosive gas:. 5065 5069 Hydroboration. J. R. Elliott, W. L. Roth, G. F. Roedel and E. M. Boldebuck JACS 1952, 74, pp.

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